Autonomous Materials Systems

Publications

2013

Jin, H., Miller, G.M., Pety, S.J., Griffin, A.S., Stradley, D.S., Roach, D., Sottos, N.R. and White, S.R. Fracture behavior of a self-healing, toughened epoxy adhesive, Int. J. Adhes. Adhes., 44, 157-165 (2013).
Aragon, A.M., Saksena, R., Kozola, B.D., Geubelle, P.H., Christensen, K.T., White, S.R. Multi-physics optimization of three-dimensional microvascular polymeric components. J. Comput. Phys., 233, 132-147 (2013).

2012

Cho, S.H., White, S.R., Braun, P.V., Room-temperature polydimethylsiloxane-based self-healing polymers. Chem. Mater., 24(21), 4209-4214 (2012).
Hamilton, A.R., Sottos, N.R., White, S.R., Mitigation of Fatigue Damage in Self-healing Vascular Materials. Polymer, 53, 5575-5581 (2012).
Odom, S.A., Tyler, T.P., Caruso, M.M., Ritchey, J.A., Schulmerich, M.V., Robinson, S.J., Bhargava, R., Sottos, N.R., White, S.R., Hersam, M.C., Moore, J.S., Autonomic Restoration of Electrical Conductivity using Polymer-stabilized Carbon Nanotube and Graphene Microcapsules, Appl. Phys. Lett., 101, 043106 (2012).
Diesendruck, C., Steinberg, B.D., Sugai, N., Silberstein, M.N., Sottos, N.R., White, S.R., Braun, P.V., Moore, J.S. Proton-coupled Mechanochemical Transduction: A Mechanogenerated Acid. J. Am. Chem. Soc., 134, 12446-12449 (2012).
Soghrati, S., Thakre, P.R., White, S.R., Sottos, N.R., Geubelle, P.H. Computational Modeling and Design of Actively-cooled Microvascular Materials, Int. J. Heat Mass Transfer, 55, 5309-5321 (2012).
Patrick, J.F., Sottos, N.R., White, S.R. Microvascular Based Self-healing Polymeric Foam, Polymer, 53,4231-4240 (2012).
Baginska, M., Blaiszik, B.J., Merriman, R.J., Sottos, N.R., Moore, J.S., White, S.R. Autonomic Shutdown of Lithium-Ion Batteries Using Thermosresponsive Microspheres, Adv. Energy Mater., 2(5), 583-590 (2012).
Odom, S.A., Chayanupatkul, S., Blaiszik, B.J., Zhao, O., Jackson, A.C., Braun, P.V., Sottos, N.R., White, S.R., Moore, J.S. A Self-healing Conductive Ink. Adv. Mater, 24, 2578-2581 (2012).
Dong, H., Esser-Kahn, A. P., Thakre, P.R., Patrick, J.P., Sottos, N.R., White, S.R., Moore, J.S. Chemical Treatment of Poly(lactic acid) Fibers to Enhance the Rate of Thermal Depolymerization, ACS Appl. Mater. Inter., 4, 503-509, (2012).
Blaiszik, B.J., Kramer, S.L.B., Grady, M.E., McIlroy, D. A., Moore, J.S., Sottos, N.R., White, S.R. Autonomic Restoration of Electrical Conductivity, Adv. Mater., 24(3), 398-401 (2012). DOI: 10.1002/adma.201102888.
Beiermann, B.A., Kramer, S.L.B., Moore, J.S., White, S.R. and Sottos, N.R. Role of Mechanophore Orientation in Mechanochemical Reactions, ACS Macro Letters, 1, 163-166 (2012).
Jin, H., Mangun, C.L., Stradley, D.S., Moore, J.S., Sottos, N.R. and White, S.R. Self-healing Thermoset Using Encapsulated Epoxy-amine Healing Chemistry, Polymer, 53(2), 581-587 (2012).
Hamilton, A.R., Sottos, N.R., White, S.R. Pressurized Vascular Systems for Self-healing Materials, J. R. Soc. Interface 9(70), 1020-1028 (2012).

2011

Odom, S.A., Jackson, A.C., Prokup, A.M., Chayanupatkul, S., Sottos, N.R., White, S.R., Moore, J.S. Visual Indication of Mechanical Damage Using Core-Shell Microcapsules, Appl. Mater. Interfaces, 3, 4547-4551 (2011). DOI: 10.1021/am201048a.
Wilson, G.O., Caruso, M.M., Schelkopf, S.R., Sottos, N.R., White, S.R., Moore, J.S. Adhesion-Promotion via Non-Covalent Interactions in Self-Healing Polymers, ACS Appl. Mater. Inter., 3, 3072-3077 (2011). DOI: 10.1021/am200584z
Esser-Kahn, A.P.. Odom, S.A.. Sottos, N.R., White, S.R., Moore, J.S. Triggered Release from Polymer Capsules Macromolecules, 44, 5539-5553 (2011). DOI:10.1021/ma201014n.
Beiermann, B.A., Davis, D.A., Kramer, S.L.B., Moore, J.S., Sottos, N.R., White, S.R., Environmental Effects on Mechanochemical Activation of Spiropyran in Linear PMMA, J. Mater. Chem., 21, 8443-8447 (2011).
White, S.R., Blaiszik, B.J., Kramer, S.L.B., Olugebefola, S.C., Moore, J.S., Sottos, N.R. Self-healing Polymers and Composites, American Scientist, 99, 392 (2011). DOI: 101511/2011.92.392
Esser-Kahn, A.P., Thakre, P.R, Dong, H., Patrick, J.F., Vlasko-Vlasov, V.K., Sottos, N.R., Moore, J.S. and White, S.R.Three-Dimensional Microvascu lar Fiber-Reinforced Composites, Advanced Materials (2011). DOI: 10.1002/adma.201100933
Esser-Kahn, A.P., Odom, S.A.; Sottos, N.R., White, S.R., Moore, J.S. Triggered Release from Polymer Capsules Macromolecules. 44, 5539-5553 (2011). DOI: 10.1021/ma201014n
Jin, H., Miller, G.M., Sottos, N.R., White, S.R. Fracture and Fatigue Response of a Self-Healing Epoxy Adhesive, Polymers, 52, 1628-1634 (2011). DOI: 10.1016/j.polymer.2011.02.011
Kingsbury, C.M., May, P.A., Davis, D.A., White, S.R., Moore, J.S. and Sottos, N.R. Shear activation of mechanophore-crosslinked polymers, Journal of Materials Chemistry, (2011). DOI: 10.1039/c0jm04015k

2010

Olugebefola, S.C., Aragon, A.M., Hansen, C.J., Hamilton, A.R., Kozola, B.D., Wu, W., Geubelle, P.H., Lewis, J.A., Sottos, N.R. and White, S.R. Polymer Microvascular Network Composites, Journal of Composite Materials, 44, 2578-2603 (2010). DOI: 10.1177/0021998310371537
Hamilton, A.R., Sottos, N.R. and White, S.R. Self-Healing of Internal Damage in Synthetic Vascular Materials, Advanced Materials, xx, 1-5 (2010). DOI: 10.1002/adma.201002561
Lee, C.K., Davis, D.A., White, S. R., Moore, J.S., Sottos, N. R. and Braun, P.V. Forced Redistribution of a Chemical Equilibrium, JACS, 132, 16107-16111 (2010). DOI: 10.1021/JA106332G
Jackson, A.C., Bartelt, J.A., Marczewski, K., Sottos, N.R. and Braun, P.V. Silica-Protected Micron and Sub-Micron Capsules and Particles for Self-Healing at the Microscale, Macromolecular Rapid Communications, 31, 1-7 (2010). DOI: 10.1002/marc.201000468
Esser-Kahn, A.P., Sottos, N.R., White, S.R. and Moore, J.S. Programmable Microcapsules from Self-Immolative Polymers, Journal of the American Chemical Society, 132, 10266-10268 (2010). DOI: 10.1021/ja104812p Selected for Faculty of 1000 Biology
Blaiszik, B.J., Kramer, S.L.B., Olugebefola, S.C., Moore, J.S., Sottos, N.R. and White, S.R. Self-Healing Polymers and Composites, Annual Review of Materials Research, 40, 179-211 (2010). DOI: 10.1146/annurev-matsci-070909-104532
Blaiszik B.J., Baginska, M., White S.R., and Sottos N.R. Autonomic Recovery of Fiber/Matrix Interfacial Bond Strength in a Model Composite, Advanced Functional Materials, 20, 3547-3554 (2010). DOI: 10.1002/adfm.201000798
Odom, S.A., Caruso, M.M., Finke, A.D., Prokup, A.M., Ritchey, J.A., Leonard, J.H., White, S.R., Sottos, N.R. and Moore, J.S. Restoration of Conductivity with TTF-TCNQ Charge-Transfer Salts, Advanced Functional Materials, 20, 1721-1727 (2010). DOI: 10.1002/adfm.201000159
McIlroy, D.A., Blaiszik, B.J., Caruso, M.M., White, S.R., Moore, J.S. and Sottos, N.R. Microencapsulation of a reactive liquid-phase amine for self-healing epoxy composites, Macromolecules, 43, 1855-1859 (2010). DOI: 10.1021/ma902251n
Kryger, M.J., Ong, M.T., Odom, S.A., Sottos, N.R., White, S.R., Martinez, T.J. and Moore, J.S. Masked Cyoanoacrylates Unveiled by Mechanical Force, Journal of American Chemical Society, 132, 4558-4559 (2010). DOI: 10.1021/ja1008932
Caruso, M.M., Blaiszik, B.J., Jin, H., Schelkopf, S.R., Stradley, D.S., Sottos, N.R., White, S.R. and Moore, J.S. Robust Double-Walled Microcapsules for Self-Healing Polymeric Materials, Applied Materials and Interfaces, 2, 1195-1199 (2010).
Moll, J.L., White, S.R. and Sottos, N.R. A self-sealing fiber-reinforced composite, Journal of Composite Materials, 44, 2573-2585 (2010). DOI: 10.177/0021998306356605
Hamilton, A.R., Sottos, N.R. and White, S.R. Local strain concentrations in a microvascular network, Experimental Mechanics, 50, 255-263 (2010). DOI: 10.1007/s11340-009-9299-5

2009

Patel, A.J., Sottos, N.R., Wetzel, E.D. and White, S.R. Autonomic healing of low-velocity impact damage in fiber-reinforced composites, Composites: Part A 41, 360-368 (2009). DOI: 10.1016/j.compositesa.2009.11.002
Hansen, C., Wu, W., Toohey, K.S., Sottos, N.R., White, S.R. and Lewis, J.A. Self-healing materials with interpenetrating microvascular networks, Advanced Materials 21, 1-5 (2009). DOI: 10.1002/adma.200900588
Kirkby, E.L., Michaud, V.J., Sottos, N.R., White, S.R. and Manson, J.-A.E. Performance of a self-healing epoxy with microencapsulated healing agent and shape memory alloy wiresPolymer, 50, 5533-5538 (2009). DOI: 10.1016/j.polymer.2009.05.014
Caruso, M.M., Davis, D.A. Shen, Q., Odom, S.A., Sottos, N.R., White, S.R. and Moore, J.S. Mechanically-Induced Chemical Changes in Polymeric Materials, Chemical Reviews (2009). DOI: 10.1021/cr9001353
Wilson, G.O., Porter, K.A., Weissman, H., Wilson, S.R., White, S.R., Sottos, N.R. and Moore, J.S. Stability of second generation grubbs' alkylidenes to primary amines: formation of novel ruthenium-amine complexes, Advanced Synthesis & Catalysis 351, 1817-1825 (2009). DOI: 10.1002/adsc.200900134
Davis, D.A., Hamilton, A., Yang, Y., Cremar, L.D., Gough, D.V., Potisek, S.L., Ong, M.T., Braun, P.V., Martínez, T.J., White, S.R., Moore, J.S. and Sottos, N.R. Force-Induced Activation of Covalent Bonds in Mechanoresponsive Polymeric Materials, Nature 459, 68-72 (2009). DOI: 10.1038/nature07970
Toohey, K.S., Hansen, C., Sottos, N.R., Lewis, J.A. and White, S.R. Delivery of two-part self-healing chemistry via microvascular networks, Advanced Functional Materials 19, 1-7 (2009). DOI: 10.1002/adfm.200801824
Blaiszik, B.J., Caruso, M.M., McILroy, D., Moore, J., White, S.R. and Sottos, N.R., Microcapsules filled with reactive solutions for self-healing materials, Polymer 50, 990-997 (2009). DOI:10.1016/j.polymer.2008.12.040
Cho, S.H., White, S.R. and Braun, P.V., Self-Healing Polymer Coatings, Advanced Materials 21, 645-649 (2009).
Toohey, K., Sottos, N.R. and White, S.R., Characterization of microvascular-based self-healing coatings, Experimental Mechanics 49, 707-717 (2009).

2008

Aragon, A.M., Wayer, J.K., Geubelle, P.H., Goldberg, D.E., White, S.R., Design of microvascular flow networks using multi-objective genetic algorithms, Computational Methods in Engineering 197, 4399-4410 (2008).
White, S.R., Caruso, M.M, Moore, J.S. Autonomic healing of polymers, MRS Bulletin 33, 766-769 (2008).
Yang, J., Keller, M.W., White, S.R. and Sottos, N.R., Microencapsulation of Isocyanates for Self-Healing Polymers, Macromolecules 41, 9650-9655 (2008). DOI: 10.1021/ma801718v
Mookhoek, S.D., Blaiszik, B.J., Fisher, H.R., Sottos, N.R., White, S.R. and van der Zwaag, S., Peripherally decorated binary microcapsules containing two liquids, Journal of Materials Chemistry 18, 5390-5394, (2008). DOI: 10.1039/b810542a
Youngblood, J., Extrand, C. and Sottos, N.R., Bioinspired Materials for Self-Cleaning and Self Healing, MRS Bulletin 33, 732-741 (2008).
Kirkby, E., Michaud, V., Manson, J.A., Rule, J., Sottos, N.R. and White, S.R., Embedded Shape-Memory Alloy Wires for Improved Performance of Self-Healing Polymers, Advanced Functional Materials 18, 2253-2260 (2008). DOI: 10.1002/adfm.200701208
Caruso, M.M., Blaiszik, B.J., White, S.R., Sottos, N.R. and Moore, J.S., Full recovery of fracture toughness using a non-toxic solvent-based self-healing system, Advanced Functional Materials 18, 1898-1904 (2008). DOI: 10.1002/adfm
Keller, M.W., White, S.R. and Sottos, N.R., Torsion fatigue of a self-healing poly(dimethyl siloxane) elastomer, Polymer 49, 3136-3145 (2008). DOI: 10.1016/j.polymer.2008.04.041
Wilson, G.O., Caruso, M.M., Reimer, N.T., White, S.R., Sottos, N.R. and Moore, J.S. Evaluation of Ruthenium Catalysts for Ring-Opening Metathesis Polymerization-Based Self-Healing Applications, Chemistry of Materials 20, 3288-3297 (2008). DOI: 10.1021/cm702933h
Blaiszik, B.J., Sottos, N.R. and White, S.R. Nanocapsules for Self-Healing Materials, Composite Science and Technology 68, 978-986 (2008).
Kamphaus, J.M., Rule, J.D., Moore, J.S., Sottos, N.R., and White, S.R., A new self-healing epoxy with tungsten (VI) chloride catalyst, J. Royal Society: Interface 5, 95-103 (2008).
Wilson, G.O., Moore, J.S., White, S.R., Sottos, N.R., and Andersson, H.M., Autonomic Healing of Epoxy Vinyl Esters via Ring Opening Metathesis Polymerization, Advanced Functional Materials 18, 44-52 (2008) .

2007

Caruso, M.M., Delafuente, D.A., Ho, V., Moore, J.S., Sottos, N.R., and White, S.R., Solvent-Promoted Self-Healing Materials, Macromolecules 40, 8830-8832 (2007).
Potisek, S., Davis, D.A., Sottos, N.R., White, S.R. and Moore, J.S., Mechanophore-Linked Addition Polymers, JACS 129, 13808-13809 (2007).
Keller, M.K., White, S.R., and Sottos, N.R., A self-healing poly(dimethyl siloxane) elastomer, Adv. Func. Materials, 17, 2399-2404 (2007).
Toohey, K.S., Sottos, N.R., Lewis, J.A., Moore, J.S., and White, S.R., Self-healing materials with microvascular networks, Nature Materials, 6, 581-585 (2007).
Rule, J.D., Sottos, N.R., White, S.R. Effect of microcapsule size on the performance of self-healing polymers, Polymer, 48, 3520-3529 (2007).
C.R. Hickenboth, J.S. Moore, S.R. White, N.R. Sottos, J. Baudry, S.R. Wilson, ''Biasing reaction pathways with mechanical force'', Nature, 446, 2007, pp. 423-427.
D. Therriault, S.R. White, J.A. Lewis, ''Rheological behavior of fugitive organic inks for direct-write assembly'', Applied Rheology, 17, 2007.
A.S. Jones, J.D. Rule, J.S. Moore, N.R. Sottos, S.R. White, ''Life extension of self-healing polymers with rapidly growing fatigue cracks'', J. Royal Society: Interface, 4(13), 2007, pp. 395-403.
Sottos, N., White, S., and Bond, I. Introduction: Self-healing polymers and composites, Special Issue. J. Royal Society: Interface 4 347-348 (2007).
T.C. Mauldin, J.D. Rule, N.R. Sottos, S.R. White, J.S. Moore, ''Self-healing kinetics and the stereoisomers of dicyclopentadiene'', J. Royal Society: Interface, 4(13), 2007, pp. 389-393.
O’Brien, D.J., Sottos, N.R. and White, S.W., Cure-dependent Viscoelastic Poisson’s Ratio of Epoxy, Experimental Mechanics,47, 237-249 (2007).

2006

S.H. Cho, H.M. Andersson, S.R. White, N.R. Sottos, P.V. Braun, ''Polydimethylsiloxane-based self-healing materials'', Advanced Materials, 18, 2006, pp. 997-1000.
A.S. Jones, J.D. Rule, J.S. Moore, S.R. White, N.R. Sottos, ''Catalyst morphology and dissolution kinetics for self-healing polymers'', Chemistry of Materials, 18, 2006, pp. 1312-1317.
E.N. Brown, S.R. White, N. R. Sottos, ''Fatigue crack propagation in microcapsule toughened epoxy'', Journal of Materials Science, 41, 2006, pp. 6266-6273.

2005

J.D. Rule, E.N. Brown, N.R. Sottos, S.R. White, J.S. Moore, ''Wax-protected catalyst microspheres for efficient self-healing materials'', Advanced Materials, 17(2), 2005, pp. 205-208.
J.D. Rule, N.R. Sottos, S.R. White, J.S. Moore, ''The chemistry of self-healing polymers'', Education in Chemistry, 42(5), 2005, pp. 130-132.
E.N. Brown, S.R. White, N.R. Sottos, ''Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite - Part 1: Manual infiltration'', Composites Science and Technology, Special Anniversary Issue, 65, 2005, pp. 2466-2473.
E.N. Brown, S.R. White, N.R. Sottos, ''Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite - Part 2: In situ self-healing'', Composites Science and Technology, Special Anniversary Issue, 65, 2005, pp. 2474-2480.
D. Therriault, R.F. Shephard, S.R. White, J.A. Lewis, ''Fugitive inks for direct-write assembly of three-dimensional microvascular networks'', Advanced Materials, 17(4), 2005, pp. 395-399.

2004

E.N. Brown, S.R. White, N.R. Sottos, ''Microcapsule induced toughening in a self-healing polymer composite'', Journal of Materials Science, 39, 2004, pp. 1703-1710.

2003

M.R. Kessler, N.R. Sottos, S.R. White, ''Self-healing structural composite materials'', Composites Part A: Applied Science and Manufacturing, 34(8), 2003, pp. 743-753.
E.N. Brown, M.R. Kessler, N.R. Sottos, S.R. White, ''In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene'', Journal of Microencapsulation, 20(6), 2003, pp. 719-730.
D. Therriault, S.R. White, J.A. Lewis, ''Chaotic mixing in three-dimensional microvascular networks fabricated by direct-write assembly'', Nature Materials, 2(4), 2003, pp. 265-271.

2002

M.R. Kessler, S.R. White, ''Cure kinetics of the ring-opening metathesis polymerization of dicyclopentadiene'', Journal of Polymer Science: Part A: Polymer Chemistry, 40(14), 2002, pp. 2373-2383.
E.N. Brown, N.R. Sottos, S.R. White, ''Fracture testing of a self-healing polymer composite'', Experimental Mechanics, 42(4), 2002, pp. 372-379.
E.N. Brown, ''Interdisciplinary research: A student's perspective'', Journal of Chemical Education, 79(1), 2002, pp. 13-14.
J.D. Rule, J.S. Moore, ''ROMP Reactivity of endo- and exo-Dicyclopentadiene'', Macromolecules, 35(21), 2002, pp. 7878-7882.

2001

M.R. Kessler, S.R. White, ''Self-activated healing of delamination damage in woven composites'', Composites Part A: Applied Science and Manufacturing, 32(5), 2001, pp. 683-699.
R. Wool, ''A material fix'', Nature, 2001 409, 794-797.
S.R. White, N.R. Sottos, J. Moore, P. Geubelle, M. Kessler, E. Brown, S. Suresh, S. Viswanathan, ''Autonomic healing of polymer composites'', Nature, 409, 2001, pp. 794-797.