Autonomous Materials Systems

Publications

2009

Hansen, C., Wu, W., Toohey, K.S., Sottos, N.R., White, S.R. and Lewis, J.A. Self-healing materials with interpenetrating microvascular networks, Advanced Materials, 21, 1-5 (2009). DOI: 10.1002/adma.200900588
Kirkby, E.L., Michaud, V.J., Sottos, N.R., White, S.R. and Manson, J.-A.E. Performance of a self-healing epoxy with microencapsulated healing agent and shape memory alloy wires, Polymer, 50, 5533-5538 (2009). DOI: 10.1016/j.polymer.2009.05.014
Caruso, M.M., Davis, D.A. Shen, Q., Odom, S.A., Sottos, N.R., White, S.R. and Moore, J.S. Mechanically-Induced Chemical Changes in Polymeric Materials, Chemical Reviews (2009). DOI: 10.1021/cr9001353
Wilson, G.O., Porter, K.A., Weissman, H., Wilson, S.R., White, S.R., Sottos, N.R. and Moore, J.S. Stability of second generation grubbs' alkylidenes to primary amines: formation of novel ruthenium-amine complexes, Advanced Synthesis & Catalysis, 351, 1817-1825 (2009). DOI: 10.1002/adsc.200900134
Davis, D.A., Hamilton, A., Yang, Y., Cremar, L.D., Gough, D.V., Potisek, S.L., Ong, M.T., Braun, P.V., Martínez, T.J., White, S.R., Moore, J.S. and Sottos, N.R. Force-Induced Activation of Covalent Bonds in Mechanoresponsive Polymeric Materials, Nature, 459, 68-72 (2009). DOI: 10.1038/nature07970
Toohey, K.S., Hansen, C., Sottos, N.R., Lewis, J.A. and White, S.R. Delivery of two-part self-healing chemistry via microvascular networks, Advanced Functional Materials, 19, 1-7 (2009). DOI: 10.1002/adfm.200801824
Blaiszik, B.J., Caruso, M.M., McILroy, D., Moore, J., White, S.R. and Sottos, N.R., Microcapsules filled with reactive solutions for self-healing materials, Polymer 50, 990-997 (2009). DOI:10.1016/j.polymer.2008.12.040
Cho, S.H., White, S.R. and Braun, P.V., Self-Healing Polymer Coatings, Advanced Materials 21, 645-649 (2009).
Toohey, K., Sottos, N.R. and White, S.R., Characterization of microvascular-based self-healing coatings, Experimental Mechanics, 49, 707-717 (2009).

2008

Aragon, A.M., Wayer, J.K., Geubelle, P.H., Goldberg, D.E., White, S.R., “Design of microvascular flow networks using multi-objective genetic algorithms,” Computational Methods in Engineering, 197:4399-4410 (2008).
White, S.R., Caruso, M.M, Moore, J.S. Autonomic healing of polymers, MRS Bulletin, 33:766-769 (2008)
Yang, J., Keller, M.W., White, S.R. and Sottos, N.R., Microencapsulation of Isocyanates for Self-Healing Polymers, Macromolecules 41, 9650-9655 (2008). DOI: 10.1021/ma801718v
Mookhoek, S.D., Blaiszik, B.J., Fisher, H.R., Sottos, N.R., White, S.R. and van der Zwaag, S., Peripherally decorated binary microcapsules containing two liquids, Journal of Materials Chemistry 18, 5390-5394, (2008). DOI: 10.1039/b810542a
Youngblood, J., Extrand, C. and Sottos, N.R., Bioinspired Materials for Self-Cleaning and Self Healing, MRS Bulletin 33, 732-741 (2008).
Kirkby, E., Michaud, V., Manson, J.A., Rule, J., Sottos, N.R. and White, S.R., Embedded Shape-Memory Alloy Wires for Improved Performance of Self-Healing Polymers, Advanced Functional Materials 18, 2253-2260 (2008). DOI: 10.1002/adfm.200701208
Caruso, M.M., Blaiszik, B.J., White, S.R., Sottos, N.R. and Moore, J.S., Full recovery of fracture toughness using a non-toxic solvent-based self-healing system, Advanced Functional Materials 18, 1898-1904 (2008). DOI: 10.1002/adfm
Keller, M.W., White, S.R. and Sottos, N.R., Torsion fatigue of a self-healing poly(dimethyl siloxane) elastomer, Polymer 49, 3136-3145 (2008). DOI: 10.1016/j.polymer.2008.04.041
Wilson, G.O., Caruso, M.M., Reimer, N.T., White, S.R., Sottos, N.R. and Moore, J.S. Evaluation of Ruthenium Catalysts for Ring-Opening Metathesis Polymerization-Based Self-Healing Applications, Chemistry of Materials 20, 3288-3297 (2008). DOI: 10.1021/cm702933h
Blaiszik, B.J., Sottos, N.R. and White, S.R. Nanocapsules for Self-Healing Materials, Composite Science and Technology 68, 978-986 (2008).
Kamphaus, J.M., Rule, J.D., Moore, J.S., Sottos, N.R., and White, S.R., A new self-healing epoxy with tungsten (VI) chloride catalyst, J. Royal Society: Interface 5, 95-103 (2008).
Wilson, G.O., Moore, J.S., White, S.R., Sottos, N.R., and Andersson, H.M., Autonomic Healing of Epoxy Vinyl Esters via Ring Opening Metathesis Polymerization, Advanced Functional Materials 18, 44-52 (2008) .

2007

Caruso, M.M., Delafuente, D.A., Ho, V., Moore, J.S., Sottos, N.R., and White, S.R., Solvent-Promoted Self-Healing Materials, Macromolecules 40, 8830-8832 (2007).
Potisek, S., Davis, D.A., Sottos, N.R., White, S.R. and Moore, J.S., Mechanophore-Linked Addition Polymers, JACS 129, 13808-13809 (2007).
Keller, M.K., White, S.R., and Sottos, N.R., A self-healing poly(dimethyl siloxane) elastomer, Adv. Func. Materials, 17, 2399-2404 (2007).
Toohey, K.S., Sottos, N.R., Lewis, J.A., Moore, J.S., and White, S.R., Self-healing materials with microvascular networks, Nature Materials, 6, 581-585 (2007).
Rule, J.D., Sottos, N.R., White, S.R. Effect of microcapsule size on the performance of self-healing polymers, Polymer, 48, 3520-3529 (2007).
C.R. Hickenboth, J.S. Moore, S.R. White, N.R. Sottos, J. Baudry, S.R. Wilson, ''Biasing reaction pathways with mechanical force'', Nature, 446, 2007, pp. 423-427.
D. Therriault, S.R. White, J.A. Lewis, ''Rheological behavior of fugitive organic inks for direct-write assembly'', Applied Rheology, 17, 2007.
A.S. Jones, J.D. Rule, J.S. Moore, N.R. Sottos, S.R. White, ''Life extension of self-healing polymers with rapidly growing fatigue cracks'', J. Royal Society: Interface, 4(13), 2007, pp. 395-403.
Sottos, N., White, S., and Bond, I. Introduction: Self-healing polymers and composites, Special Issue. J. Royal Society: Interface 4 347-348 (2007).
T.C. Mauldin, J.D. Rule, N.R. Sottos, S.R. White, J.S. Moore, ''Self-healing kinetics and the stereoisomers of dicyclopentadiene'', J. Royal Society: Interface, 4(13), 2007, pp. 389-393.
O’Brien, D.J., Sottos, N.R. and White, S.W., Cure-dependent Viscoelastic Poisson’s Ratio of Epoxy, Experimental Mechanics,47, 237-249 (2007).

2006

S.H. Cho, H.M. Andersson, S.R. White, N.R. Sottos, P.V. Braun, ''Polydimethylsiloxane-based self-healing materials'', Advanced Materials, 18, 2006, pp. 997-1000.
A.S. Jones, J.D. Rule, J.S. Moore, S.R. White, N.R. Sottos, ''Catalyst morphology and dissolution kinetics for self-healing polymers'', Chemistry of Materials, 18, 2006, pp. 1312-1317.
E.N. Brown, S.R. White, N. R. Sottos, ''Fatigue crack propagation in microcapsule toughened epoxy'', Journal of Materials Science, 41, 2006, pp. 6266-6273.

2005

J.D. Rule, E.N. Brown, N.R. Sottos, S.R. White, J.S. Moore, ''Wax-protected catalyst microspheres for efficient self-healing materials'', Advanced Materials, 17(2), 2005, pp. 205-208.
J.D. Rule, N.R. Sottos, S.R. White, J.S. Moore, ''The chemistry of self-healing polymers'', Education in Chemistry, 42(5), 2005, pp. 130-132.
E.N. Brown, S.R. White, N.R. Sottos, ''Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite - Part 1: Manual infiltration'', Composites Science and Technology, Special Anniversary Issue, 65, 2005, pp. 2466-2473.
E.N. Brown, S.R. White, N.R. Sottos, ''Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite - Part 2: In situ self-healing'', Composites Science and Technology, Special Anniversary Issue, 65, 2005, pp. 2474-2480.
D. Therriault, R.F. Shephard, S.R. White, J.A. Lewis, ''Fugitive inks for direct-write assembly of three-dimensional microvascular networks'', Advanced Materials, 17(4), 2005, pp. 395-399.

2004

E.N. Brown, S.R. White, N.R. Sottos, ''Microcapsule induced toughening in a self-healing polymer composite'', Journal of Materials Science, 39, 2004, pp. 1703-1710.

2003

M.R. Kessler, N.R. Sottos, S.R. White, ''Self-healing structural composite materials'', Composites Part A: Applied Science and Manufacturing, 34(8), 2003, pp. 743-753.
E.N. Brown, M.R. Kessler, N.R. Sottos, S.R. White, ''In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene'', Journal of Microencapsulation, 20(6), 2003, pp. 719-730.
D. Therriault, S.R. White, J.A. Lewis, ''Chaotic mixing in three-dimensional microvascular networks fabricated by direct-write assembly'', Nature Materials, 2(4), 2003, pp. 265-271.

2002

M.R. Kessler, S.R. White, ''Cure kinetics of the ring-opening metathesis polymerization of dicyclopentadiene'', Journal of Polymer Science: Part A: Polymer Chemistry, 40(14), 2002, pp. 2373-2383.
E.N. Brown, N.R. Sottos, S.R. White, ''Fracture testing of a self-healing polymer composite'', Experimental Mechanics, 42(4), 2002, pp. 372-379.
E.N. Brown, ''Interdisciplinary research: A student's perspective'', Journal of Chemical Education, 79(1), 2002, pp. 13-14.
J.D. Rule, J.S. Moore, ''ROMP Reactivity of endo- and exo-Dicyclopentadiene'', Macromolecules, 35(21), 2002, pp. 7878-7882.

2001

M.R. Kessler, S.R. White, ''Self-activated healing of delamination damage in woven composites'', Composites Part A: Applied Science and Manufacturing, 32(5), 2001, pp. 683-699.
R. Wool, ''A material fix'', Nature, 2001 409, 794-797.
S.R. White, N.R. Sottos, J. Moore, P. Geubelle, M. Kessler, E. Brown, S. Suresh, S. Viswanathan, ''Autonomic healing of polymer composites'', Nature, 409, 2001, pp. 794-797.